Vincent Gandon Institut de Chimie Moléculaire et des Matériaux dOrsay, UMR 8182 Université Paris-sud Mécanismes réctionnels en catalyse homogène : Assistance de la chimie théorique Les simulations numériques en chimie à Paris-sud 24 octobre 2012
Asymmetric Carbocyclizations: Chiral Anion Strategy
DFT, G 298 (kcal/mol) B3LYP/LANL2DZ/6-31G**
Asymmetric Carbocyclizations: Chiral Anion Strategy Chem. Eur. J. 2011, 17, 13789
Cyclization of Diynyl Esters
ACIE 2011, 6868 DFT, H 298 (kcal/mol) B3LYP/LANL2DZ/6-31G** Cyclization of Diynyl Esters
OL 2007, Allene Gold Complexes
Linear Triquinanes: Synthesis of 9(12) -Capnellene JACS 2009, 2993
1 -Allene Gold Complexes
AuBr DFT, H 298 (kcal/mol) B3LYP/LANL2DZ/6-31G** 1 -Allene Gold Complexes
AuBr DFT, H 298 (kcal/mol) B3LYP/LANL2DZ/6-31G** 1 -Allene Gold Complexes
Chirality Transfers ACIE 2008, 7534
exo-Cyclizations ACIE 2006, 7596
Toste, Houk JACS 2008, 4517 exo-Cyclizations
Polynuclear Gold Complexes
Mass spectroscopy (CAR) Polynuclear Gold Complexes
Intermediacy of Gold Acetylides?
Chem. Sci. 2011, 2, 2417 DFT, G 298 (kcal/mol) B3LYP/LANL2DZ/6-31G**
Facilities Paris 6CRIHAN ICSN IDA