Presentation On CRUDE OIL CHARACTERISTICS. Petroleum/Crude Natural occurring hydrocarbon found below the surface of the earth. oil “Crude Oil” means all.

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1 Presentation On CRUDE OIL CHARACTERISTICS

2 Petroleum/Crude Natural occurring hydrocarbon found below the surface of the earth. oil “Crude Oil” means all kinds of hydrocarbons in liquid form in their natural state or obtained by Natural Gas bycondensationor extraction. It isa hydrocarbon mixture having simple to most complex structures such as resins, asphaltenes etc. Crudeoilisformedbybacterial transformation of Organic matter (carbohydrates/proteins/from plant & animal origin) by decay in presence and/or absence ofairinto HC rich sedimentsbyundergoing biological/physical and chemical alterations

3 Chemical Carbon Hydrogen Sulphur Nitrogen Oxygen Metals Composition 83.0 to 87.0% 10.0 to 14.0 % 0.05 to 6.0 % 0.1 to 2.0 % 0.05 to 1.5 % 0.00 to 0.14 %

4 CrudeOilCharacterization TRADING: Density, API Gravity TRANSPORTATION:RVP, Pour Point, KV, Wax content Salt content, BS&W Sulfur, Nitrogen, TAN, Asphaltene, MCR ASTM Distillation Light hydrocarbons (GC) CONTAMINATION PROCESSABILITY :::: CRACKING POINT LPG POTENTIAL CLASSIFICATION :::: : Characterization factor

5 WorldCrudeOilQuality Properties of Crude Oil 1985199019952001 2010 (Proj) ‘S’ in crude Oil (wt%) 1.141.121.311.411.51 API Gravity of Crude oil 32.732.632.432.231.8 Metal in crude oil Residue (ppm wt) 275286297309320 Residue in crude (vol%) 1919.419.820.221.3 ‘S’ in crude oil residue (wt%) 3.073.263.613.914.0

6 CrudeOil EvaluationScheme ALL TESTS ARE CONDUCTED ASPER STANDARD TEST METHODS : ASTM/IP/IS SR 540- 600C+ Vac Gas Oil 370-540/600C Atm.Resid 370C+ Gas oil 240-370C Kero 140-240C Naphtha C5-140C TBP Distillation

7 PropertiesofCrudeoil 27 31.4 Characteristics Basrah Light Bombay High Arab mixKuwaitNorth Gujarat Density, gm/ml API gravity Pour point, o C Kinematic Viscosity @40@40 o C @50@50 o C Water content, %wt Salt content, ptb Sulphur, %wt TAN, mgKOH/gm CCR, %wt Wax, %wt Asphaltene, %wt ASTMDistillation cracking point, o C Metal content, ppm Nickel/vanadium 0.8745 30.3 -30 - - nil 10 3.1 - 5.9 1.2 2.6 339 - 0.8200 41.0 21 3.4 - nil - 0.09 0.1 1.1 12.7 0.25 372 - 0.8664 31.6 -24 10.0 8.9 nil L20 2.7 0.14 6.4 2.5 2.3 322 4/23 0.8741 30.3 -27 11.1 8.5 nil 2.0 2.8 0.14 5.4 6.0 2.5 335 4/33 0.8932 26.8 65.6 4.1 200 0.08 1.93 2.5 5.9 0.05 367 61/L10

8 APIGravity API Gravity API =(141.5/sp.gravity)-131.5 Light Crude Oil Mixed Based Heavy crude >31 22-31 <22 API is a majorfactorfor Crudepricing

9 BS&W Base sediments and Water determined by Karl Fischer titration using a Met Rohm 701 KF Automatic Titrator (ASTM D 4377) or by Distillation method, ASTM D4006 Oils with significant water contents, (>5%), represent the properties of the "dry" oil. donot

10 Flash Point flashpointsand fire pointsof lubricating oilscanbe determined by ASTM method D 92/IP 170  Many fresh crude oils have flash points below 10 o C and/or viscosities above 9.5 cSt at 25 o C

11 PourPoint  The pour point of an oil is the lowest temperature at which the oil will just flow, under standard test conditions. The pour pointof the oils is therefore anindication,andnotanexactmeasure,ofthe temperature at which flowceases.  ASTM method D 97 - Standard Test Method for Pour Point ofPetroleumOils(ASTM,1996a) pour point determinations.  Heavy & waxy oil transportation is a challenge

12 Viscosity There are several ASTM Standard Methods for measuring  theviscosityofoils. Of these, onlymethodsD445 - ofo f StandardTestMethod Opaque forKinematicViscosity Calculatio n TransparentandLiquids(the Dynamic Viscosity) and D 4486 - Standard Test for Kinematic Viscosity of Volatile and Reactive Method Liquids, (ASTM, willyieldabsolute viscosity measurements 1996a).  Bothofthesemethodsmake and use of glass capillary absolute kinematicviscometerswillproduce measurementsinunits of centistokes (cSt)onlyfor oils thatexhibitNewtonianflowbehavior(viscosity independent ofthe rate of shear).

13 Products Fuel Oil (High S, Low S) LPG Naphtha Fuel Oil (High or low Viscosity) LSHS HPS Petrol (BS-II/BSIII) Kerosene ATF Diesel (BS-II/BS-III) LOBS Bitumen RPC Wax Petrochemical feed LABFS HPL Naphtha stock Petrochemicals pX, PTA LAB etc

14 THANK YOU!!!