ENVE 420 Industrial Pollution Control ADSORPTION Applications for Industrial Wastes Dr. Aslıhan Kerç.

Slides:



Advertisements
Présentations similaires
Laboratoire de Bioinformatique des Génomes et des Réseaux Université Libre de Bruxelles, Belgique Introduction Statistics.
Advertisements

NAME: Abdul Saleem Mir Enrollment Number: 49/2010 7th ELECTRICAL
%mass %volume Composition of concrete Concrete cement water sand
Nommez les composés. Qu’est-ce qu’on fait!?! RévisionCharges ionique Creez les composés Nommez les composés Les propriétées physiques des composés NaCl.
Clique Percolation Method (CPM)
Le Chatelier's Principle Lesson 2. Le Chatelier’s Principle If a system in equilibrium is subjected to a change processes occur that oppose the imposed.
Making PowerPoint Slides Avoiding the Pitfalls of Bad Slides.
PERFORMANCE One important issue in networking is the performance of the network—how good is it? We discuss quality of service, an overall measurement.
PIPE SUPPORTS 1 Pipe supports inside the compression station and pumping stations AUGUST 2014.
« Petit Suisse » Nutrition value Packaging Price.
V. Microbiology of water V. Microbiology of water A. Waterborne microbial pathogens B. Indicator bacteria for drinking water C. Other indicators for drinking.
An Introduction To Two – Port Networks The University of Tennessee Electrical and Computer Engineering Knoxville, TN wlg.
Electronic Instrumentation Lecturer Touseef Yaqoob1 Sensors and Instrumentation Sensors and Instrumentation.
 Components have ratings  Ratings can be Voltage, Current or Power (Volts, Amps or Watts  If a Current of Power rating is exceeded the component overheats.
IP Multicast Text available on
Template Provided By Genigraphics – Replace This Text With Your Title John Smith, MD 1 ; Jane Doe, PhD 2 ; Frederick Smith, MD, PhD 1,2 1.
DIFFUSION IN SOLIDS  FICK’S LAWS  KIRKENDALL EFFECT  ATOMIC MECHANISMS Diffusion in Solids P.G. Shewmon McGraw-Hill, New York (1963)
From Implementing Cisco IP Routing (ROUTE) Foundation Learning Guide by Diane Teare, Bob Vachon and Rick Graziani ( ) Copyright © 2015 Cisco Systems,
UNEP / ICCA Workshop TEMA June DG and GHS Classification System.
Subject: CMS(Content Management System) Université Alioune DIOP de Bambey UFR Sciences Appliquées et Technologies de l’Information et de la Communication.
Design of Facilities for Physical, Chemical & Biological Treatment of Waste Water Bibhabasu Mohanty Asst. Prof. Dept. of civil Engineering SALITER, Ahmedabad.
WASTE WATER AND ITS TREATMENT IN TEXTILE INDUSTRY VANDANA TRIPATHI.
Pharmaceutical Waste Treatment and Disposal Practices Part I: Treatment of Pharmaceutical Wastewater Dr. Alaadin A. Bukhari Centre for Environment and.
Brazing TCSPM jaw (Sept. 2016)
Speaking Exam Preparation
Réunion service Instrumentation Activités CMS-Traces
Reflective verbs or Pronominal verbs
GROUP FOUR OF DIPLOMA CIVIL “A”. Presentation On Fuel & Combustion Submitted By Submitted To Group4 Mr Tarang Agarwal Sir Diploma Civil A.
Quantum Computer A New Era of Future Computing Ahmed WAFDI ??????
the Periodic Table the Periodic Table 2017/2018 Made by : NEDJAR NASSIMA Made by : NEDJAR NASSIMA MS:HAMZA 1.
Statistics & Econometrics Statistics & Econometrics Statistics & Econometrics Statistics & Econometrics Statistics & Econometrics Statistics & Econometrics.
Innovative Plants For a green and technologic future.
Biogas Background Basic Terminology Stages of the Biogas Process Industrial Process Purification of CH4 1.
NFPA-12 Edition 2005 What “IMPACT” will the changes to NFPA-12 have on the design and installation of a CO 2 system?
© 2004 Prentice-Hall, Inc.Chap 4-1 Basic Business Statistics (9 th Edition) Chapter 4 Basic Probability.
Copyright 2007 – Biz/ed Globalisation.
P&ID SYMBOLS. P&IDs Piping and Instrumentation Diagrams or simply P&IDs are the “schematics” used in the field of instrumentation and control (Automation)
Realized by :  ZDOUKI Issam  EL OUAKILI Mourda  SOUJAA Mohamed Amine Ask by:  Prof.ELMARZGUIOUI Salwa.
NO x is a generic term for the nitrogen oxides that are most relevant for air pollution, namely nitric oxide (NO) and nitrogen dioxide (NO 2 ).These gases.
Integrated Gasification Combined Cycle Plant By Abhijit Kumar Prasad Submitted to Dr. B.Paul Assistant Professor MNNIT Allahabad.
“Confidential –Internal Halliburton Use Only. © 2004 Halliburton. All Rights Reserved.” Stimulation Techniques Fracturing Fluids Proppants.
CENTRIFUGAL PUMP CHARACTERISTICS CE 370. Types of Pumps There are different types of pumps which are used for different purposes in water and wastewater.
1 ISO/TC 176/SC 2/N1219 ISO 9001:2015 Revision overview - General users July 2014.
Metallic Glasses in Cell Phones Angelika Franz. Outline what is a metallic glass structure properties processing cell phone cases cell phone hinges.
G. Peter Zhang Neurocomputing 50 (2003) 159–175 link Time series forecasting using a hybrid ARIMA and neural network model Presented by Trent Goughnour.
Lect12EEE 2021 Differential Equation Solutions of Transient Circuits Dr. Holbert March 3, 2008.
Essai
Presentation On CRUDE OIL CHARACTERISTICS. Petroleum/Crude Natural occurring hydrocarbon found below the surface of the earth. oil “Crude Oil” means all.
Introduction to Computational Journalism: Thinking Computationally JOUR479V/779V – Computational Journalism University of Maryland, College Park Nick Diakopoulos,
High-Availability Linux Services And Newtork Administration Bourbita Mahdi 2016.
Français - couleurs - pays - drapeaux
Forum national sur l’IMT de 2004.
Definition Division of labour (or specialisation) takes place when a worker specialises in producing a good or a part of a good.
Roots of a Polynomial: Root of a polynomial is the value of the independent variable at which the polynomial intersects the horizontal axis (the function.
Connaissez-vous la France ?
Manometer lower pressure higher pressure P1P1 PaPa height 750 mm Hg 130 mm higher pressure 880 mm Hg P a = h = +- lower pressure 620 mm Hg.
What’s the weather like?
Analyses thermiques Le comportement thermique a été tudié par ATG et ATD afin de prévoir la température et les conditions de calcination nécessaire à l'obtention.
Presented by : HAMDI Yosra Faculty of science of Bizerte 1 1.
Making PowerPoint Slides Avoiding the Pitfalls of Bad Slides.
By : HOUSNA hebbaz Computer NetWork. Plane What is Computer Network? Type of Network Protocols Topology.
1 of 29© Boardworks Ltd of 29© Boardworks Ltd 2008.
1 Sensitivity Analysis Introduction to Sensitivity Analysis Introduction to Sensitivity Analysis Graphical Sensitivity Analysis Graphical Sensitivity Analysis.
Avoiding the Pitfalls of Bad Slides Tips to be Covered Outlines Slide Structure Fonts Colour Background Graphs Spelling and Grammar Conclusions Questions.
Le Passé Composé (Perfect Tense)
Les Mots Intérrogatifs
University : Ammar Telidji Laghouat Faculty : Technology Department : Electronics 3rd year Telecommunications Professor : S.Benghouini Student: Tadj Souad.
D’Accord 1 Leçon 3A.1 Descriptive adjectives (irregular adjectives, adjective placement-BAGS, and physical description.)
IMPROVING PF’s M&E APPROACH AND LEARNING STRATEGY Sylvain N’CHO M&E Manager IPA-Cote d’Ivoire.
M’SILA University Information Communication Sciences and technology
Transcription de la présentation:

ENVE 420 Industrial Pollution Control ADSORPTION Applications for Industrial Wastes Dr. Aslıhan Kerç

Adsorption Equilibrium Adsorption vs. Absorption –Adsorption is accumulation / adhesion of molecules at the surface of a solid material (usually activated carbon) in contact with an air or water phase –Absorption is dissolution of molecules within a phase, e.g., within an organic phase in contact with an air or water phase

Adsorption Absorption (“partitioning”) PHASE I PHASE 2 PHASE I ‘PHASE’ 2 Henry’s Law

The Jargon of Adsorption

Causes of Adsorption Dislike of Water Phase – ‘Hydrophobicity’ Attraction to the Sorbent Surface –van der Waals forces: physical attraction –electrostatic forces (surface charge interaction) –chemical forces (e.g.,  - and hydrogen bonding)

The surface of a solid shows a strong affinity for molecules that come into contact with it. Certain solid materials concentrate specific substances from a solution onto their surfaces. Adsorption Phenomenon Physical adsorption (physisorption): Physical attractive forces (van der Waals forces) e.g. Carbon ads, Activated alumina Adsorption Phenomenon Chemical adsorption (chemisorption): the adsorbed molecules are held to the surface by covalent forces. (little application in ww treatment)

Adsorbents in Natural & Engineered Systems Natural Systems –Sediments –Soils Engineered Systems –Activated carbon –Metal oxides (iron and aluminum as coagulants) –Ion exchange resins –Biosolids

Engineered Systems - Removal Objectives Activated carbon (chemical functional groups) –Adsorption of organics (esp. hydrophobic) –Chemical reduction of oxidants Metal oxides (surface charge depends on pH) –Adsorption of natural organic matter (NOM) –Adsorption of inorganics (both cations & anions) Ion exchange resins –Cations and anions –Hardness removal (Ca 2+, Mg 2+ ) –Arsenic (various negatively charged species), NO 3 -, Ba 2+ removal

Activated Carbon Systems Carbon systems generally consist of vessels in which granular carbon is placed, forming a filter bed through which ww passes.

Activated Carbon Systems Area requirement: less If anaerobic conditions occur  Biological activity in carbon beds  H 2 S formation Spent Carbon  land disposal problem, unless regenerated Regeneration systems  Expensive + Air pollution problems

Activated Carbon

Activated Carbon Systems Pretreatment is important to reduce solids loading to granular C systems. Powdered Activated Carbon (PAC) can be fed to ww using chemical feed equipment.

Activated Carbon Systems Mostly used for organic matter removal. AC remove variety of organics from water (not selective) Metal removal: Recent applications in metal removal Few in full scale Pretreatment by sedimentation / filtration to remove precipitated metals Remaining dissolved metals adhere to the carbon until all available sites are exhausted. Spent carbon  Replaced with new or regenerated C

Factors effecting Carbon Adsorption Physical and chemical characteristics of carbon (surface area, pore size) Physical and chemical characteristics of adsorbate ? (molecular size, molecular polarity, chemical composition) Higher molecular weight  more easily adsorbed Molecular weight  Size

Factors effecting Carbon Adsorption Concentration of adsorbate in the liquid phase (solution) Characteristics of the liquid phase ? (pH, temperature) Contact time Increasing solubility of the solute in the liquid carrier decreases adsorbability Branched chains are usually more adsorbable than straight chains

Factors effecting Carbon Adsorption Substituent groups (hydroxyl, amino, carbonyl groups, double bonds) Molecules with low polarity are more sorbable than highly polar ones.

Oxygen-Containing Surface Groups on Activated Carbon Mattson and Mark, Activated Carbon, Dekker, 1971

Steps in Preparation of Activated Carbon Pyrolysis – heat in absence of oxygen to form graphitic char Activation – expose to air or steam; partial oxidation forms oxygen-containing surface groups and lots of tiny pores

Properties of of Ativated Carbon Made from: (?) - Wood - Lignin - Bituminous coal - Lignite - Petroleum residues Standards for specific applications: - Pore size - Surface area - Bulk density

Factors Affecting Activated Carbon Properties Starting materials (e.g., coal vs. wood based) and activation Pores and pore size distributions Internal surface area Surface chemistry (esp. polarity) Apparent density Particle Size: Granular vs. Powdered (GAC vs. PAC)

Characteristics of Some Granular Activated Carbons Characteristics of Activated Carbons (Zimmer, 1988) Activated CarbonF 300 H 71 C25 Raw Material Bituminous CoalLigniteCoconut Shell Bed Density, ρ F (kg/m 3 ) Particle Density, ρ P (kg/m 3 ) Particle Radius (mm) Surface Area BET (m 2 /g) Pore Volume (cm 3 /g) Micro Meso Macro Total ( radius < 1nm) (1nm < r < 25nm) (radius > 25nm)

Other parameters used for AC characterization Phenol Number: Index of carbon’s ability to remove taste and odor compouns Iodine Number: Adsorption of low- molecular weight substances Micropores, radius <2 µm Molasses Number: Carbon’s ability to adsorb high molecular weight substances Pores 1 – 50 µm

Other parameters used for AC characterization High iodine number  Effective for ww with low molecular weight organics High molases number  Effective for ww with high molecular weight organics

Kinetics of Atrazine Sorption onto GAC

Carbon Regeneration Objective: Remove the previously adsorbed materials from the carbon pore structure Methods: - Thermal - Steam - Solvent extraction - Acid / base treatment - Chemical Oxidation

Thermal Regeneration Drying Desorption High temperature heat treatment (650 – 980 o C) in the presence of water vapor, flue gas, oxygen - Multiple heat furnaces - Fluidized bed furnaces are used.

Adsorption Isotherms Technical feasibility of Activated Carbon ↓ Adsorption tests ↓ Generate adsorption isotherms

Adsorption Isotherms Technical feasibility of Activated Carbon ↓ Adsorption tests ↓ Generate adsorption isotherms

Adsorptive Equilibration in a Porous Adsorbent Adsorbed Molecule Diffusing Molecule Equilibrium Pore GAC Particle Early Later Laminar Boundary Layer

Adsorption Isotherms Add Same Initial Target Chemical Concentration, C init, in each Different activated carbon dosage, C solid, in each Control An adsorption ‘isotherm’ is a q vs. c relationship at equilibrium

Metal Oxide Surfaces Coagulants form precipitates of Fe(OH) 3 and Al(OH) 3 which have –OH surface groups that can adsorb humics and many metals Humic substances where R is organic

Sorption of NOM on Metal Oxide

Sorption of Metals on Metal Oxide SOH + Me 2+  SOMe + + H +

Ion Exchange Resins 2R  -Na + + Ca 2+  R 2 -Ca + 2Na + R + -Cl  + H 2 AsO 4   R + - H 2 AsO 4  + Cl 

If mineral surface started with q >0: Assuming mineral surface started with q = 0:

Commonly Reported Adsorption Isotherms Linear:Langmuir: Freundlich:

Shape of Langmuir Isotherm

Shape of Freundlich Isotherm

Shape of Freundlich Isotherm (log scale)

Example. Adsorption of benzene onto activated carbon has been reported to obey the following Freundlich isotherm equation, where c is in mg/L and q is in mg/g: A solution at 25 o C containing 0.50 mg/L benzene is to be treated in a batch process to reduce the concentration to less than 0.01 mg/L. The adsorbent is activated carbon with a specific surface area of 650 m 2 /g. Compute the required activated carbon dose. Solution. The adsorption density of benzene in equilibrium with c eq of mg/L can be determined from the isotherm expression: A mass balance on the contaminant can then be written and solved for the activated carbon dose:

Example If the same adsorbent dose is used to treat a solution containing mg/L toluene, what will the equilibrium concentration and adsorption density be? The adsorption isotherm for toluene is: Solution. The mass balance on toluene is:

General Process Design Features Contactors provide large surface area Types of contactors –Continuous flow, slurry reactors –Batch slurry reactors (infrequently) –Continuous flow, packed bed reactors Product water concentration may be –Steady state or –Unsteady state

PAC + Coagulants Sludge Withdrawal PAC particles may or may not be equilibrated Settled Water PAC + Coagulants Flocculated Water Powdered Activated Carbon (PAC) Process Operates at Steady-State, c out = constant in time

Packed Bed Adsorption v, c IN Natural Packed Bed – subsurface with groundwater flow Engineered Packed Bed- granular activated carbon EBCT = empty-bed contact time (V bed /Q) v, c OUT Adsorptive capacity is finite (fixed amount of adsorbent in bed) Process operates at unsteady state, c OUT must increase over time